三亚湾滨珊瑚中的重金属及环境意义

利用ICP AES测定了海南岛三亚湾滨珊瑚(Porites)骨骼生长带1978～1999年Cr、Zn、Cd、Cu、Pb的质量分数。结果表明,珊瑚骨骼内重金属平均质量分数顺序为:Cu>Zn>Pb>Cd>Cr,重金属的富集系数顺序为:Cd>Pb>Cu>Cr>Zn。1978～1988间,珊瑚骨骼重金属质量分数相对稳定,此后除Cr逐年减少外,Zn、Cd、Cu、Pb增加,尤以1995年以来的增加幅度显著。珊瑚骨骼重金属质量分数反映了表层海水重金属浓度的变化,表明90年代中后期以来三亚湾海区海水重金属污染有明显恶化的趋势。     

基于半参数分析的电力需求预测算法

市场经济对电力需求预测提出了更高的要求。在简要介绍和评论以往国内外常用电力需求预测方法优缺点基础上,为了提高电力需求预测的准确度及预测方法的适应性,建立半参数回归模型预测电力需求。半参数回归模型分为线性和非线性两部分。线性部分反映了负荷预测可知的部分规律,非线性部分反映了负荷预测的不确定因素的影响。用偏残差方法估计半参数回归模型,估计结果由两步得到。首先估计线性参数部分,然后再估计非线性参数部分。通过示例计算,半参数回归模型对电力需求预测的估计误差数值小于二元线性回归法对电力需求预测的估计误差。结果表明:利用半参数回归法预测电力需求是一种预测精度高、计算容易、普适性强的算法。     

An Analysis of the Daily Radial Activity of 7 Boreal Tree Species, Northwestern Quebec

In the `Des Vieux Arbres' ecological reserve situated within northwestern Québec, 40 band dendrometers were installedon 7 of the major boreal tree species. The late Spring–early Summer daily radial activity registered in 1997 was related todaily weather variables. For each tree species, the daily mean i) cumulative radial increment and ii) radial activity indexedseries obtained by first-difference standardization were analyzed. The results indicate the existence of strong similarities among the 7 species. All showed strong synchronousfluctuations in radius during late winter and early spring. Thisperiod ended with a short but sharp increase in radial increments that marked the passage of water into the stem. Thisinitial swelling, less obvious in Pinus species was followed by a prolonged period of little change in radial activity. Meteorological data indicated that air temperature waspositively related to stem swelling during the late winter–earlyspring period. Both air and soil temperatures became negatively related to radial expansion once the passage of water has occurred in the stem. Starting in early June, all species registered a sustained increase in radial increments possiblyassociated with active cell division. After this, radial expansion was negatively related to air temperature and positively to rainfall.     

Visible light induced photodegradation of organic pollutants on nitrogen and fluorine co-doped TiO2 photocatalyst

The nitrogen and fluorine co-doped TiO2 polycrystalline powder was synthesized by calcinations of the hydrolysis product of tetrabutyl titanate with ammonium fluoride. Nitrogen and fluorine co-doping causes the absorption edge of TiO2 to shift to a lower energy region.The photocatalytic activity of co-doped TiO2 with anatase phases was found to be 2.4 times higher than that of the commercial TiO2 photocatalyst Degussa P‘25 for phenol decomposition under visible light irradiation. The co-doped TiO2 powders only contain anatase phases even at 1000%. Apparently, ammonium fluoride added retarded phase transformation of the TiO2 powders from anatase to futile.The substitutional fluorine and interstitial nitrogen atoms in co-doped TiO2 polycrystalline powder were responsible for the vis light response and caused the absorption edge of TiO2 to shift to a lower energy region.     

51CrV4弹簧钢环箍断裂失效分析

目的研究51Cr V4弹簧钢环箍出现断裂失效原因。方法通过化学成分分析、力学性能分析、断口扫描分析、显微组织分析及能谱分析测试手段,对51Cr V4弹簧钢环箍的断裂模式及失效原因进行分析。结果长时间处于拉应力状态,致使51Cr V4弹簧钢环箍内表面棱边萌生裂纹源;同时,在腐蚀介质和应力的协同作用下,S元素加速腐蚀进程,腐蚀产物积累,加快腐蚀微裂纹的扩展,最终导致应力腐蚀断裂失效的发生。结论通过合理的选材、结构设计和防护工艺,严格控制原材料成分,降低应力水平和环境严苛度,使应力腐蚀出现概率大大减小。     

含硬夹矸高瓦斯低透气性煤层多向聚能爆破技术研究

针对在含硬夹矸高瓦斯低透气性煤层开采时，一方面煤层瓦斯抽采困难，另一方面煤层中的坚硬夹矸难破碎的问题，开展含硬夹矸高瓦斯低透气性煤层多向聚能爆破研究。理论上，分析多向聚能装药对爆破的影响，引入多向聚能影响系数，计算得出了不同方向上裂隙的范围。通过相似模拟试验，验证了多向聚能爆破实际效果；利用LS-DYNA数值模拟软件，对不同装药方式爆破作用下煤与夹矸裂隙的发育特征及应力演化规律进行了数值模拟研究。研究结果表明:多向聚能爆破能够将爆破能量积聚在夹矸弱化和煤层增透的方向上，形成以导向裂隙为主，大量分支裂隙为辅的裂隙网，在夹矸弱化和煤层增透方向上的应力峰值分别为普通爆破的1.21倍和1.16倍。多向聚能爆破能够在提高破碎坚硬夹矸能力的同时提升煤体中裂隙的发育程度，从而大幅优化爆破效果。     

污水处理工程中的裂缝控制

讨论了在污水处理工程中,钢筋混凝土结构裂缝产生的原因,提出了具体的裂缝控制措施。     

基于高光谱分形分析的水稻镉污染动态监测

水稻中过量镉会影响叶绿素含量和细胞结构,进而改变水稻在光谱维上的特征表现.利用长春郊区实测大田水稻高光谱数据和同步测量的土壤、水稻生化参数,系统分析水稻冠层光谱曲线的分形特征及不同镉污染胁迫程度下光谱分维与两类光谱指数的变化情况,构建光谱分维、光谱指数与水稻叶片镉浓度的空间分布图,探讨光谱分维与光谱指数在提取镉污染胁迫等级信息中的相互关系及物理机制.研究表明,光谱分维相对于光谱指数能够更好地综合反映镉污染胁迫下水稻生理特征参数的变化,因而为有效地大范围动态监测水稻镉污染提供诊断依据.     

条形基础砂土地基的破坏模型试验

为了研究条形基础砂土地基的剪切破坏形式和承载机理,在相似理论的指导下,进行了一组条形基础砂土地基的模型试验,模拟了砂土地基受荷后产生变形、扩展直到破坏的全过程;测量并分析了地基中不同点处的土压力大小及其分布规律,观测了剪切带的形成和发展过程。结果表明,模型试验能够很好地体现砂土地基变形、破坏的整个过程及其沉降变形特性、地基中各点的真实应力状态及其变化规律,对于研究深基坑变形过程和破坏形态具有应用价值。